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equilibrium systems

shift in directions that minimize stresses

restore a new equilibrium

exposed to external stress

increase of concentration of reactants

more collisions

reactant particles

the forward reaction is favored

an increase of products

the system reaches a new equilibrium

the equilibrium law

changes in concentration

the reactants are favored

K << 1

the denominator of the fraction (reactants) is greater than the numerator

the equilibrium constant "K" of the system remains the same

a new equilibrium is achieved with different concentrations of chemicals

the products are favored

K >> 1

the numerator of the fraction (products) is greater than the denominator

changes in temperature

the forward reaction is endothermic and temperature increases

K increases

the system shifts to increase the product side (numerator)

the equilibrium constant "K" of the system changes

a new equilibrium is achieved with a new temperature of the system

the value of the equilibrium constant is only temperature dependent

the forward reaction is exothermic and temperature increases

K decreases

the system shifts to increase the reactant side (denominator)

decrease in temperature of the system

the system must shift

produce more energy

the exothermic reaction side is favored

an increase of the release of energy