Denaturation of DNA

Hydrogen bonds among base pairs are disturbed

Hypo-chromic effect

stacked bases in DNA reduce absorption of UV light

UV absorption of DNA increases when back stacking is lost

denatured DNA can be detected by monitoring UV absoprtion

Renaturation of partially denatured DNA

Strands spontaneously anneal when temperature and pH returns to normal range

In DNA replication and transcription

catalyzed by enzymes

Renaturation of completely denatured DNA

Two step process

1st step (Slow step)

By random collisions strands find each other

2nd (fast step)

spontaneous annealing of unpaired bases

In DNA Replication and transcription

A-T base pairs in DNA are denatured while G-T remain intact to imitate strand separation

called bubbles

Catalyzed by enzymes

partial denatuation

Occurs at high temperatures and extreme changes in pH

temperature is characteristic to each species of DNA

DNA rich in Guanine - Cytosine base pairs

denatures at very high temperatures

DNA rich in Adenine - Thymine base pairs

denatures at lower temperatures

Viral and Bacterial DNA

Denature at slowing heating Temperatures

Back-stacking is lost