Unit 3 chemistry
Phase change Terminology
Melting: From a solid to a liquid ; heat is added
Solidification: From a liquid to a solid; heat is removed; also called fusion
Sublimation: From a solid to a Gas
Depositions: Gas to Solid phase change
Evaporation: Liquid to gas; heat added
Definite shape, Definite Volume, Highly Organized
Energy
Definition:
Intermolecular Forces (IMF's)
Specific heat capacity
Subtopic
They're Forces that act between stable molecules
Solid: Strong IMF, so low entropy
Liquid: Moderate IMF, so moderate entropy
Gas: Low IMF, so high Entropy
Thermal energy
equation Q=mc^t
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Q: heat energy (Joules or calories)
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M: mass (g)
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C: Specific heat capacity
How mush energy it takes to heat up one gram of a substance by one degree Celsius
Specific heat: The higher the specific heat, the more energy is needed to heat up the substance/ Lower the specific heat= the less energy is needed
^t: Change in Temperature (Celsius)
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Difference between Temperature and heat
Temperature: Average Kinetic energy of particles in a substance
Hotter substances having faster moving particles
Units for temperature: Celsius does not work for gas laws so Kelvins should be used K= Celsius + 273
Matter
Liquid
Indefinite Shape, Definite Volume, Less Organized
Solid
Gas
Indefinite Shape, Indefinite Volume, Very Disorganized
Plasma
A Gas heated up so intensely that the electrons break away from their distinct atoms
In order from Solids to a Gas is the Increase in Entropy and Kinetic Energy
Entropy: How much "Chaos" in the molecules of a substance
Units of Pressure
Atmospheres (ATM): Normal atmospheric pressure is one atm
KiloPascals (kPa): The normal atmospheric pressure for this is 101.325 kPa
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Volume
Definition: the amount of space a gas takes up; measured in Liters (L) for gases; possibly measured in mL; 1L=1000 mL
Assumptions made for ideal gases
Particles have no volume
Particles have no intermolecular forces
Particles are in constant motion and travel randomly in straight lines, bouncing off one another
Gas laws
Boyles Law: As pressure increases, volume decreases; P1 V1= P2V2
Charle's Law: As gas temperature increases, Volume increases; equation is V1/T1= V2/T2
Combined gas law: It is a combination of Boyle's and Charles' law, where one of the values does not always have to e constant, so you may use any variables
Dalton's Laws of partial pressure: If you have a mixture of gases, the total pressure is the sum is all the pressures of each gas; P total= (P1+P2+........)
phase Diagram:
Critical pressure: occurs at 218 atm in water
Normal freezing point: 32 degrees fahrenheit or 273.15 Kelvin
Triple point: It is that temperature and pressure at which the sublimation curve, fusion curve and the vaporization curve meet. or the temperature and pressure at which the solid, liquid, and vapor phases of a pure substance can coexist in equilibrium.
Normal boiling point: It's the temperature at which a liquid boils at 1 atmosphere of pressure.
Critical point: the point on the phase diagram at which both the liquid and gas phases of a substance have the same density, which means they are indistinguishable.
Ideal gas law; PV=nRT
Pressure (atm or kPa)
Volume: (L or mL)
Number of Moles of the gas (mol or Mole)
R: Gas constant
Temperature (k)