Emulsfier
Type of emulsion
o/w eg. Milk
w/o eg. Margarine
Factors affect stability of an emulsion
•Degree of division of the inner phase
•Quality/stability of the interfacial film
•Viscosity of the outer phase
•Ratio & the specific weight of the volumes of the two phases
Function of emulsifier
•As surfactant
•Starch complex forming ability
•Modifying ability for oils and fats
•Protein modifying ability
•Antibacterial and antifungal
•Plasticizing
Type of emulsifier
Non-ionic (uncharged)
•Mono- and diglycerides
•Sorbitan esters
•Sucrose esters
•Polysorbates
•Polyoxyethylene glycol oleates
(all contain an – oh functional group)
Anionic (negative electrical charges)
•Stearoyl lactylates
•Diacetyl tartaric esters of monoglycerides (DATEM)
•Succinylated monoglycerides
Cationic (positive electrical charges) *toxic
•Amine compounds
Amphoteric (both positive and negative charges)
•Various lecithins
Stabilization of emulsion through… (actions)
Increase interfacial tension
(with surface active properties)
Ionic interaction (DLVO theory)
By fine particle
-Powdered silica
-Basic salt
-Plant fragment
By macromolecules
(physical barrier to coalescence)
-Protein
-Gum
Emulsion destabilization
•Creaming
•Flocculation
•Coalescence
•Ostwald ripening
Hydrophilic-lipophilic balance (HLB)
-High lipophilic-low HLB (1-10)
-High hydrophilic-high HLB (>10)
Function of emulsifier in foods
Bakery and other starch products
•Crumb softener
•Volume enhancer
•Dough conditioner
Cake and sponge improver
•Ensure good fat distribution in batter
•Aid moisture retention in finished cakes
•Facilitate mechanical handling
•Improve aeration and volume
•Better texture and shelf life
Pasta products and snacks
•Improve texture
•Reduce stickiness
•Aid extrusion
•Impart crispness
Potatoes
•Improve texture and whip
•Reduce stickiness
Peanut butter
•Inhibit oil separation