Gums & Stabilizers
Function
Primary Functions
Thickening agent
Gelling agent
Secondary Functions
Stabilization of emulsion
Suspension of particulate
Control of crystallisation
Encapsulation
Formation of film
Factors affect its properties
Degree of substitution (DS)
High- Faster to hydrate
Low - Slower to hydrate
Degree of Polymerization (DP)
High - higher viscosity,slower to hydrate
Low - Lower viscosity, faster to hydrate
Molecular weight
Monosaccharide composition
Types of side chain
Number of side chain
Distribution of side chain
Main topic
Subtopic
Sources of raw materials
Pectin
-from citrus fruits
-Natural - protopectin
High Methoxy Pectin (HMP)
(DE>/= 50%)
-58% - 75%
-To form gel
soluble solid content = 55-85%
pH = 2.8-3.8
Exp : jams & jellies
-Gels at hogh solid low pH
-DE high,easy form gel
-not heat reversible
Rapid/Ultrapid set pectin
-in jams with whole fruits
Slow set pectin
-very acid fruits
-Exp : blackcurrent (to prevent gelation)
Low Methoxy Pectin (LMP)
-DE<50%
-required Calcium ions
-wide pH range (1-7)
-heat reversible gel
Conventional low methoxy pectin (LMP)
-less Ca ions reactive
-as thickening agent - yoghurt fruit
Amidated Low Methoxy Pectin (ALMP)
-very Ca ions reactive
-gelation in low sugar fruit
Carageenan
-from seaweed
-no emulsifier property
Kappa-carageenan
thermoreversible gel
Lambda-carageenan
non-thermoreversible gel
Iota-carageenan
thermoreversible gel
Alginate
-mannuronic acid and guloronic acid
form gel in cold water
thermo-ireversible gel
Propylene glycol alginate - stabiliser in emulsion
Xanthan gum
from fermentation of CHO
Completely soluble in cold water & produce high viscosiy at low concentration
good heat and pH stablity
viscosity unchanges
-temp 0-100
-pH 1-13
Locust bean gum
insoluble in cold water
must heated to dissolve
maximum viscosity - 95 degree celcius
not form gel by itself
form gel when with xanthan gum
non-ionic
stable over pH3.5-11.0
thickening agent , stabilization of emulsion, inhibition of syneresis
Guar gum
more soluble & hydrate fully in cold water
high viscosity
viscosity builder
as stabilizer
water binder
Stable at pH 4-10
Gum Arabic
=gum acacia
dissolve easily in cold water
least viscous
most soluble
as encapsulation agent
as emulsifier & stabilizer
Properties
non-gelling
gelling
thermoreversible gel
non-thermoreversible gel