Categorías: Todo - bases - acids - systems - reactions

por Rameen Sarwar hace 5 meses

39

Equillibrium

The concept of chemical equilibrium is fundamental in both theoretical and practical chemistry, impacting various systems ranging from biochemical pathways to industrial processes. In the context of acids and bases, the Bronsted-Lowry theory defines acids as proton donors and bases as proton acceptors.

Equillibrium

Equillibrium

Le chatellier's principle

Catalysts: Affect the rate of reaching equilibrium but not the position of equilibrium.
Pressure: For gaseous reactions, increasing pressure shifts equilibrium towards the side with fewer moles of gas.
Temperature: Changing temperature affects the equilibrium position depending on whether the reaction is exothermic or endothermic.
Concentration: Adding/removing reactants or products shifts the equilibrium.
Principle: If a system at equilibrium is disturbed by changing conditions, the system will adjust to counteract the disturbance and restore a new equilibrium.

Equilibrium Calculations

ICE Tables: Initial, Change, Equilibrium approach for solving equilibrium problems.
Using K: Solve for unknown concentrations or equilibrium positions.
K = [Products]/[Reactants]

Impact of Chemical Equilibrium on Systems

Technological Systems: Industrial synthesis (e.g., Haber process), pollution control, manufacturing processes.
Biochemical Systems: Metabolic pathways, drug interactions.
Biological Systems: Enzyme-catalyzed reactions, pH regulation in blood.

Bronsted-Lowry Theory

Dynamic Equilibrium: In weak acids/bases, equilibrium is established between the acid/base and its conjugate base/acid.
Weak Acids/Bases: Partially dissociate (low Kₐ or K_b).
Strong Acids/Bases: Completely dissociate in water (high Kₐ or K_b).
Bases: Proton acceptors (H⁺)
Acids: Proton donors (H⁺)

Dynamic Equillibrium

Ongoing Reactions: Both forward and reverse reactions occur continuously.
Constant Concentrations: Not equal, but steady over time.
Definition: A state in a reversible reaction where the rates of the forward and reverse reactions are equal, so concentrations of reactants and products remain constant.