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Sequential chemical analysis
In small quantities
ppb=(Mass of solute (g)) x10^9 (Mass of solution (g))
ppm=(Mass of solute (g)) x10^6 (Mass of solution (g))
%=(Volume of solute (ml)) x100% (Volume of solution (mL))
%=(Mass of solute (g)) x100% (Mass of solution (g))
%=(Mass of solute (g)) x100% (Volume of solution (mL))
C=Amount of solute(n) Volume of solution(L)
A substance that turns red litmus paper blue
Dissociates in water to form [OH-] ions
8-11
pH and [H+] concentration
pH of 7
10^-pH
-log[H+]
Temp vs g dissolved per 100g of H2O
Supersaturated solution
Saturated solution
Unsaturated solution
Polar dissolves polar, ionic and polar substances can be dissolved in polar
Ionic substances with + and - parts get pulled apart by polar substances
Vmolar=24.8L/mol
Vmolar=22.4L/mol
P1V1=P2V2 T1 T2
n=PV RT
Ideal gas constant: 8.31 kPaL/molK
P1=P2 T1 T2
V1=V2 T1 T2
P1V1=P2V2
Neils Bohr
James Chadwick
Ernst Rutherford
Alpha, Beta, Gamma Rays
Electronegativity determines polarity
J.J. Thomson
Mendeleev's periodic law: Elements arranged by increasing atomic mass
Modern periodic law: Elements arranged by increasing atomic number
Vertically, by Group
-Nuclear charge increases -Shielding effect increases -Atomic radius increases -Ionization energy decreases -Electronegativity decreases -Electron affinity decreases
More protons in nucleus means greater attraction of valence electrons
Repulsion of valence electrons by inner electrons
Horizontally, by period
-Nuclear charge increases -Shielding effect is constant -Atomic radius decreases -Ionization energy increases -Electronegativity increases -Electron affinity increses
Shiny like metals, brittle like non-metals
Staircase line
Group 17: Halogens
Group 18: Noble Gases
Unreactive due to full valence shell
A metal and non-metal can form an ionic compound
Mostly solid at SATP, conduct heat and electricity well
Groups 3-12: Transition Metals
Group 2: Alkaline Earth Metals
Group 1: Alkali Metals
2 reactants, forming 2 products
Each reactant has 2 elements, molecules, polyatomic ions etc.
Halogen
Lone halogen replaces halogen in compound
Metal
Hydrogen gas and metal hydroxide OR ionic compound produced
Lone metal replaces metal in compound
Only occurs if lone metal is higher on activity series than metal in compound
Complete Combustion
Flame is blue or invisible
Incomplete Combustion
Flame is orange, black soot produced
Soot (solid carbon) and carbon monoxide
Products are CO2 gas, water vapour and energy
Exothermic reaction produces thermal energy
One product, breaking down into 2 reactants
2 reactants, forming 1 product
Stoichiometry
nwant=nhave*(#of mols want) (# of mols have)
Percentage yield
%yield=(actual yield) * 100% (theoretical yield)
Amount of product actually produced
Amount of product that could be produced
Limiting and excess reagents
nproduct=nhave*(#of mols reactant) (# of mols product)
Reactant that is not used up first
Reactant that is used up in reaction
The smaller mole product #
Empirical and molecular formulas
Finding actual # of elements in a compound
Finding simplest whole # ration of atoms/ions
Percentage composition
%xtotal=(mx/mtotal)*100%